| dc.contributor.author | Osorio-Román, Igor [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada] | es_CL |
| dc.contributor.author | Guzmán, Diego [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada] | es_CL |
| dc.contributor.author | Isaacs, Mauricio | es_CL |
| dc.contributor.author | Tsukuda, Tatsuya | es_CL |
| dc.contributor.author | Yamazoe, Seiji | es_CL |
| dc.contributor.author | Takahata, Ryo | es_CL |
| dc.contributor.author | Schrebler, Ricardo | es_CL |
| dc.contributor.author | Burgos, Ana | es_CL |
| dc.contributor.author | Castillo, Francisco | es_CL |
| dc.date.accessioned | 2020-04-12T14:11:55Z | |
| dc.date.accessioned | 2020-04-14T15:37:45Z | |
| dc.date.available | 2020-04-12T14:11:55Z | |
| dc.date.available | 2020-04-14T15:37:45Z | |
| dc.date.issued | 2020 | es_CL |
| dc.identifier.citation | Guzmán, D., Isaacs, M., Tsukuda, T., Yamazoe, S., Takahata, R., Schrebler, R., ... & Castillo, F. (2020). CdTe Quantum Dots modified electrodes ITO-(Polycation/QDs) for carbon dioxide reduction to methanol. Applied Surface Science, 145386. | es_CL |
| dc.identifier.issn | 0169-4332 | es_CL |
| dc.identifier.issn | 1873-5584 | es_CL |
| dc.identifier.uri | https://doi.org/10.1016/j.apsusc.2020.145386 | es_CL |
| dc.identifier.uri | http://repositorio.umayor.cl/xmlui/handle/sibum/6457 | |
| dc.description.abstract | The present work describes the characterization by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and electrochemical techniques of ITO modified electrodes with electrostatic assemblies (Polycation/Quantum Dots) and their use in the electro- and photoelectrocatalytic reduction of CO2. These assemblies were prepared with polycations poly-diallyldimethylammonium (PD) and poly-(2-trimethylammonium) ethyl methacrylate (PM) and nanocrystals of CdTe of 2.77 nm (Q2). The size of the nanocrystals was controlled by the synthesis reflux time and incorporated by electric field directed Layer-by-Layer assembly method (EFDLA). The polycations were characterised by NMR measurements; showing important effects on the electrostatic assemblies. PM modified electrodes, with its lower rigidity, exhibited less roughness than the PD modified electrodes, 8.0 nm versus 32.8 nm, and higher heterogeneity in its surface composition. Higher resistance to the charge transfer and time constants were obtained with PMQ2 modified electrode, 63.8 Omega cm(-2) and 2.69 ms versus 49.30 Omega cm(-2) and 1.3 ms for PDQ2. The electro- and photoelectro properties for CO 2 reduction were studied through j-E curves and potential controlled electrolysis. Modified surfaces were active toward the reduction of CO2, with a positive shift of the activity between darkness and irradiation conditions, 0.050 V with PDQ2 and 0.450 V with PMQ2. The main product of the CO2 reduction was CH3OH, with traces of CO and HCOOH. The PM modified electrodes with QDs of 2.77 nm presented a selective behaviour for the production of CH3OH. | es_CL |
| dc.description.sponsorship | FONDECYTComision Nacional de Investigacion Cientifica y Tecnologica (CONICYT)CONICYT FONDECYT [1181226, 1160485, 3160217, RC130006]; CONICYTComision Nacional de Investigacion Cientifica y Tecnologica (CONICYT) [21130425, 3170490]; Pontificia Universidad Catolica de Chile; Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT) [A-15-UT-0185] | es_CL |
| dc.description.sponsorship | This work was supported by FONDECYT 1181226, 1160485, 3160217 and RC130006 CILIS projects, CONICYT Postdoctoral 3170490 grant, CONICYT 21130425 grant, Pontificia Universidad Catolica de Chile, PIDi Universidad Tecnologica Metropolitana and"Nanotechnology Platform"(No. A-15-UT-0185) from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan. | es_CL |
| dc.language.iso | en | es_CL |
| dc.publisher | ELSEVIER | es_CL |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| dc.source | Appl. Surf. Sci., ABR, 2020. 509 | |
| dc.subject | Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter | es_CL |
| dc.title | CdTe quantum dots modified electrodes ITO-(Polycation/QDs) for carbon dioxide reduction to methanol | es_CL |
| dc.type | Artículo | es_CL |
| umayor.facultad | CIENCIAS | |
| umayor.politicas.sherpa/romeo | RoMEO green journal (Se puede archivar el pre-print y el post-print o versión de editor/PDF). Disponible en: http://sherpa.ac.uk/romeo/index.php | es_CL |
| umayor.indexado | WOS:000514827600002 | es_CL |
| umayor.indexado | SIN PMID | es_CL |
| dc.identifier.doi | DOI: 10.1016/j.apsusc.2020.145386 | es_CL] |
| umayor.indicadores.wos-(cuartil) | Q1 | es_CL |
| umayor.indicadores.scopus-(scimago-sjr) | SCIMAGO/ INDICE H: 159 H | es_CL |